2.2]decane core and defining the geometry with the exocyclic double bond. The activation energies of formation from the vinyl-gold intermediates ended up calculated and unveiled a silyl enol ether with the unprotected indole moiety as an acceptable precursor for the Toste cyclization. This six-step synthesis did not require any nonstrategic redox m
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2.2]decane Main and defining the geometry of your exocyclic double bond. The activation energies of formation in the vinyl-gold intermediates were being calculated and exposed a silyl enol ether by having an unprotected indole moiety as an acceptable precursor for your Toste cyclization. This 6-step synthesis did not involve any nonstrategic redox
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two.two]decane Main and defining the geometry with the exocyclic double bond. The activation energies of development on the vinyl-gold intermediates have been calculated and uncovered a silyl enol ether with an unprotected indole moiety as a suitable precursor for your Toste cyclization. This 6-stage synthesis didn't require any nonstrategic redox